Pre-Columbian Peruvian Metals

Sample 16

Weaving tool with cotton thread

Moche

North Coast, Peru

ca. 100-600 AD

Report by :

Kevin Elliott

May 15, 2003

Introduction
Figure 1: Weaving tool with cotton thread
 

The purpose of this study was to examine a Pre-Columbian Peruvian sample possibly used as a weaving tool, and to determine the authenticity of the sample (Sample 02-01-16). We were also interested in determining the metal composition and forming techniques of the sewing tool. The sample was found with white cotton resembling thread wrapped around the back end. A picture of the sample is given as Figure 1.

Pre-Columbian Peruvian tribes wove textiles for use as rugs, clothes and for ornamental purposes. Weaving was an important expression of art incorporating intricate designs, often including a design within a design, as well as complicated weaving methods such as going back over a single stitch three times1. Pre-Columbian Peruvians wove using functional yet simple tools resembling large needles often made of whatever metal was available, primarily copper from the copper rich Andes.

Proceedure  
The first step of the procedure was to section off two pieces of the sample in a way that damages the sample as little as possible. It became necessary to view the sample in the cross-sectional and longitudinal direction to detect any differences in microstructure revealing possible working. The second step of this process was to mount, grind, polish the sample. The sample was then etched in a chemical etch consisting of equal parts of water, ammonia, and 3% hydrogen peroxide. After etching, the microstructures of each direction were examined to offer clues to the forming process. Next, a series of tests were taken to determine the hardness of the sample to verify the forming method. Finally, an x-ray photograph was taken of the specimen in order to aid determination of the specimen's authenticity.
Figure 2: Cross-sectional view of the copper microstructure showing annealing twins, deformation twins, and circular inclusions.
Figure 3: Longitudinal view of the copper microstructure showing annealing twins, deformation twins and elongated inclusions.
Results and Discussion  
The sample is clearly of copper composition when viewed without even the aid of a microscope. Copper has a very distinctive color and a very distinctive blue-green pastel oxide color (as shown in Figure 1). When viewed with a microscope, there are many tiny inclusions visible that suggest that the metal was not perfectly pure. See Figures 2 and 3 for cross-sectional and longitudinal views of the copper microstructure. The inclusions are most likely copper oxide or another unwanted material, and this is very logical since the pre-Columbian Natives had limited means of purifying metals. This lends credence to the argument that the sample is authentic.

An analysis of both the cross-sectional and longitudinal views of the tip show similar grain size in both direction but elongated inclusions in the longitudinal direction. This leads one to believe that at least the tip of the object was hammered after being annealed. Finally, the presence of annealing twins and deformation twins can be used to determine the forming technique for the sewing tool. The sewing tool was most likely hammered from a cast copper rod while the copper was hot and then put back into the fire to anneal the grains and make the sample more workable. The annealing yields annealing twins, and the hammering after recrystallization yields the deformation twins.

Figure 4: X-Ray photograph of weaving tool.
Discussion (con't)  
Experimental evidence that the copper was cast, hammered, annealed, and then hammered again to achieve a point on the tip of the weaving tool lies within the microhardness for the sample. The expected microhardness for a pure copper cold worked sample is between 100 and 120 Vickers2. The calculated microhardness for the copper sample is 122.8 Vickers. This data is just outside the range of values for worked copper, which can be justified due to the inclusions in the copper microstructure. Additionally, values were calculated for the tip of the weaving tool which was worked vigorously to make it into a point for weaving, thus a value on the higher end of the range of values is to be expected.

The x-ray photograph taken of the specimen showed the specimen to be of the same composition throughout the tool as evidenced by the same color and shade for the entire tool. A fake sample made of a cheaper material than copper and then copper plated would not look so homogeneous when viewed in the x-ray spectrum. See Figure 4 for an x-ray photograph of the sample. A final way to determine the specimen's age and therefore authenticity, would be to carbon date the thread attached to the end as seen in Figure 1. C-14 dating of the tread, showed the tread to date between 1500-1650 which would date the piece much later than anticipated (figure 5).

Figure 5: C-14 dating of the cotton thread found on the weaving tool dates the piece to much later than anticipated.
     

References

  1. Bernstein, David. Lecture. American Museum of Natural History. 4 April 2002.
  2. Scott, David A. Metallography and Microstructures of Ancient and Historical Metals. Los Angeles: The J. Paul Getty Trust, 1991.
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This site was last updated on July 25 2003